3 Key Chemical Leavening Agents in Baking (2024)

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Baking Soda, Baking Powder and Cream of Tartar: Breaking down baking ingredients

For some reason, cold days inspire a desire to bake. Even myself, who admittedly is not a skilled baker, will trifle through the dessert sections of cookbooks looking for something scrumptiously sweet and oven-baked. This led me to ponder about certain ingredients that are the key leavening agents used in baked goods; baking soda, baking powder and cream of tartar.

The first thing you should understand about baking soda and baking powder is that they are NOT the same thing. Yes, baking soda is IN baking powder, but they are not interchangeable items. So what are they?

Baking Soda
3 Key Chemical Leavening Agents in Baking (1)Chemically known as sodium bicarbonate, baking soda is a type of salt that’s made by mixing carbon, sodium, hydrogen and oxygen molecules. It’s used to chemically leaven doughs and batters when it is mixed with an acid. Combining baking soda with an acid produces a chemical reaction that releases carbon dioxide gas which causes the food to expand and become fluffy. Think about light and airy pancakes. That’s the baking soda at work. On the other hand, if you have dense rocks for pancakes, then your baking soda might not be working.

This technique is different than using yeast to leaven bread because yeast is a biological process since it’s a living organism that produces the carbon dioxide gas from eating various carbohydrates found in the batter. Yeast are alive. Baking soda is not. But both cause products to rise by producing carbon dioxide gas, just in different ways.

And because baking soda is not a living organism, it’s pretty shelf stable for quite some time. It does not have to be refrigerated. In fact, baking soda used for cooking shouldn’t be kept it in the refrigerator because it will absorb orders lingering in that environment. Now, this is a great use for baking soda, but just don’t use that baking soda for baking and cooking anything.

Baking soda is often labeled with a best by date of 18 to 24 months, but you can always test its effectivity by mixing 1 1/2 teaspoons of baking soda in a bowl with 1 tablespoon of vinegar. It is still usable if it fizzes.

Keep in mind, baking soda becomes reactive when it’s exposed to acids (buttermilk, vinegar) and must be used right away otherwise the carbon dioxide-producing bubbles will begin to pop and result in a flat and dense product rather than something light and airy. So, it’s probably not a good idea to make and hold a batter for a long time. It’s better to use it right away (or at least within the hour) especially once the baking soda and acidic ingredient has been combined. Protecting those bubbles is also why you’ll want to mix batters lightly. Vigorous mixing will cause bubbles to break.

Baking Powder
3 Key Chemical Leavening Agents in Baking (2)This ingredient is a mixture of baking soda and powdered acids. It’s usually found in recipes that do not call for additional acids because it already contains acid. Like baking soda, it makes products rise by producing carbon dioxide gas; however, it does so in two phases. First, the baking soda in the powder along with one of the acids starts producing carbon dioxide bubbles when they’re mixed with wet ingredients. The second rising phase happens when the other powdery acid reacts with the remaining baking soda producing more bubbles when exposed to heat over 170°F. This two phase rising method is known as double-acting. There are single-acting baking powders available; these powders only rise once during the heating stage of baking. Your recipe will specifically call for single-acting baking powder if needed. Most baking powders are commonly double-acting.

Like baking soda, you can test it to see if it’s still effective. Put one teaspoon of baking powder in a small bowl and mix in one tablespoon of warm water. If the baking powder doesn’t fizz when wet, it’s no longer active and should be thrown out.

Also, like baking soda, baking powder is usually dated with a “best by” range of 18 to 24 months, but it will last indefinitely if it does not become contaminated. Contamination happens when the same measuring spoon is used to measure other ingredients before it’s used to measure the baking powder.

Don’t have baking powder? You can make your own. For every 1 teaspoon of baking powder, substitute: 1/4 teaspoon baking soda, 1/2 teaspoon cream of tartar, and 1/4 teaspoon cornstarch OR 1/4 teaspoon baking soda plus 1/2 cup buttermilk, sour milk or yogurt (for this substitution, you’ll want to decrease the liquid in the recipe by half)

Cream of Tartar
3 Key Chemical Leavening Agents in Baking (3)It’s not a cream, not does it bear any relation to the tartar one hears about during dental visits. So, what is it? It’s actually a byproduct of wine production. After wine has been fermented and aged in barrels, it leaves behind a powdery substance. That substance is harvested and purified and sold as cream of tartar. It’s primarily an acid. In fact, it’s one of the powdery acids used in baking powder to help leaven products. It also helps strengthen the structure of egg whites so they don’t deflate so quickly which is very handy when making meringues.

It is not often called for in recipes, so it’s not typically a pantry staple unless you bake a lot. An acceptable substitution is 1 1/2 teaspoons of lemon juice or vinegar.

All of these products should be stored in their original containers in a cool, dry place - not over your stove. The heat and moisture from cooking could chemically alter them.

Sources:

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3 Key Chemical Leavening Agents in Baking (2024)

FAQs

3 Key Chemical Leavening Agents in Baking? ›

leavening agent, substance causing expansion of doughs and batters by the release of gases within such mixtures, producing baked products with porous structure. Such agents include air, steam, yeast, baking powder, and baking soda.

What are 3 leavening agents? ›

leavening agent, substance causing expansion of doughs and batters by the release of gases within such mixtures, producing baked products with porous structure. Such agents include air, steam, yeast, baking powder, and baking soda.

What are 3 raising agents used in home baking? ›

Rising agents give baked goods optimal volume, texture and crumb and can include baking soda or baking powder, whipped egg whites or cream, active or instant dry yeast, and even steam.

What are the chemical raising agents in baking? ›

A common chemical raising agent used in food is baking powder, which contains two active ingredients, bicarbonate of soda (sodium bicarbonate - something called an alkali) and cream of tartar (potassium hydrogen tartrate - something called an acid).

What are the three main leavening gases in baked goods? ›

Final answer: The three main leavening gases in baked goods are carbon dioxide, ethanol, and steam, all of which contribute to the rising and texture of bakery products through processes like alcoholic fermentation by yeast.

What are chemical leaveners? ›

Chemical leaveners consist of ingredients such as baking soda, baking powder and, more rarely, baking ammonia, potash and pearl ash. These ingredients chemically react with certain ingredients in a recipe (moisture and acids) and also with heat to form air bubbles. Yeast is also a leavener that helps dough to rise.

What chemicals are involved in baking? ›

3 Key Chemical Leavening Agents in Baking
  • Baking Soda. Chemically known as sodium bicarbonate, baking soda is a type of salt that's made by mixing carbon, sodium, hydrogen and oxygen molecules. ...
  • Baking Powder. This ingredient is a mixture of baking soda and powdered acids. ...
  • Cream of Tartar.

Is yeast a chemical leavening agent? ›

Organic leavening agents (yeast microorganisms) require food, warmth, and moisture to grow. Yeasts are slow-growing plants that slowly give off carbon dioxide while consuming sugars, not as part of a chemical reaction.

What are the 3 gases used in cooking as a raising agent? ›

Four main raising agents are used in cooking:
  • Air – egg whites, beating creaming, rubbing in.
  • Steam – profiteroles,choux pastry, Yorkshire pudding.
  • Carbon dioxide – yeast fermentation, baking powder, self raising flour.
  • Chemicals – bicarbonate of soda, baking powder.
Jun 12, 2015

What is the best leavening agent? ›

The most common leavening agents are: yeast, baking powder, baking soda, and cream of tartar. However, many other standard ingredients have some lifting qualities as well, such as: well-sifted flour, eggs, yogurt, beer, or seltzer water.

Can I use baking soda instead of baking powder? ›

Remember that baking soda is 3-4 times stronger than baking powder, so you'll need a lot more baking powder to get the same leavening action. As a general rule, triple the amount of baking powder for the amount of baking soda called for in a recipe. For example, 1 teaspoon baking soda = 3 teaspoons baking powder.

Is baking soda a chemical? ›

Sodium bicarbonate, also known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO3 and the IUPAC designation sodium hydrogencarbonate.

Are eggs a leavening agent? ›

Eggs, according to multiple sources, have a great ability to leaven or puff up foods when air is beaten into them,2, 3 and that they aid in leavening overall in baking applications.

Is vinegar a leavening agent? ›

Vinegar helps with the rise of our baked goods

Firstly, vinegar helps our baked goods rise and create an airy texture by reacting with baking soda. When vinegar reacts with baking soda, it creates carbon dioxide bubbles, which act as leavening agents.

Is butter a leavening agent? ›

Leavening Agent

Solid fats, like butter, can help baked goods rise. When you cream butter and sugar together, it creates an aerated mixture that provides lift before, during, and after baking. Butter also contains water, and when the water evaporates, it creates flakey layers critical to a pie crust or biscuit.

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