Cookie chemistry (2024)

What makes a chocolate chip cookie chewy? Or crisp, or crunchy?

Cookie chemistry.

Cookie chemistry (1)

The interaction between sugar and fat and flour, baking time and temperature – plus a large measure of experimentation done right in your own kitchen – is how to nail your favorite chocolate chip cookie texture.

Let me tell you up front: I'm devoted to simplicity in food prep, and that includes baking. I don't use a cookie cutter, braid bread dough (aside from a basic 3-strand), or decorate cakes.

I put my heart and soul and brain into everything I bake – but I also put those three entities into a zillion other things important to me: like family, friends, counseling women with health issues, and volunteering at various non-profits.

Cookie chemistry (2)

So I'm not fond of trying 87 different takes on a recipe to get it exactly right.

First, I see that as a waste of time; if you can get 95% of the way there in the first three tries, you're good.

And second, having been developing recipes for King Arthur Flour for over 25 years, I know that what comes out of my home kitchen won't be exactly what comes out of yours – even when you follow the recipe exactly as written. Your oven, pans, ingredients, and even your micro-climate and the weather affect what you bake.

So here's the deal: my goal with this post is to show you how to take a basic chocolate chip cookie recipe and give it the texture you prefer: light and crunchy; thin and crisp; or soft and chewy.

More words than you could shake a spatula at have been written about "the perfect chocolate chip cookie." But what is that elusive being, anyway?

Cookie chemistry (3)

Plain and simple, the perfect chocolate chip cookie is the one you love best. So we're going to start with my favorite chocolate chip cookie recipe and, with a few simple tweaks, give you options for potentially turning it into YOUR favorite chocolate chip cookie recipe – no matter which camp your textural preference falls in: crunchy, crisp, or chewy.

Here's your beginning formula. If your favorite cookie is one that's crisp around the edges and softer in the center, stop right here: this is the recipe for you.

2/3 cup light brown sugar, firmly packed
2/3 cup granulated sugar
1/2 cup unsalted butter, right from the fridge, or at room temperature
1/2 cup vegetable shortening
3/4 teaspoon salt
2 teaspoons vanilla extract
1/4 teaspoon almond extract, optional
1 teaspoon vinegar, cider or white
1 teaspoon baking soda
1 large egg
2 cups (8 1/2 ounces) King Arthur Unbleached All-Purpose Flour
2 cups semisweet chocolate chips

Note: For complete directions, see the recipe: Chocolate Chip Cookies. I'm providing you with just the ingredients and some suggested baking temperatures/times here.

Cookie chemistry (4)

How to make crunchy chocolate chip cookies.

1. Substitute 2/3 cup granulated sugar for the brown sugar.

2. Substitute 1/2 cup vegetable shortening for the butter.

3. Bake the cookies for 23 minutes in a preheated 325°F oven.

Cookie chemistry: Crunchiness in a cookie depends on a good balance of fat and dryness. Butter contributes milk solids and water to a cookie, both of which soften it. Brown sugar contributes molasses – again, a softener.

Using lower-moisture sugar (granulated) and fat (vegetable shortening), plus a longer, slower bake than normal, produces light, crunchy cookies.

Cookie chemistry (5)

That said, using a combination of butter and vegetable shortening (as in the original recipe), or even using all butter, will make an acceptably crunchy chocolate chip cookie. It won't be AS crunchy as an all-shortening cookie; but for those who eschew vegetable shortening, it's an option.

Cookie chemistry (6)

How to make crisp chocolate chip cookies.

1. Substitute 2/3 cup granulated sugar for the brown sugar.

2. Substitute 1/2 cup butter for the vegetable shortening.

3. Bake the cookies for 30 minutes in a 325°F oven.

Cookie chemistry (7)

Cookie chemistry: The difference between a crunchy and crisp cookie is thickness; we perceive thicker cookies as crunchy, thinner cookies as crisp.

The melting temperature of butter is lower than that of shortening. As they bake, butter-based cookies start to spread before their structure is set; while those made with shortening set before the shortening reaches its melting point.

The result? In this recipe, cookies made with butter (above, left) are wider, thinner, and crispier than those based on shortening (above, right).

In addition, baking these thin cookies several minutes longer than their shortening-based counterparts transforms their innate crunchiness into crispiness.

Cookie chemistry (8)

How to make soft/chewy chocolate chip cookies.

1. Substitute 1 cup brown sugar for the 2/3 cup brown sugar and 2/3 cup granulated sugar.

2. Substitute 1/2 cup butter for the 1/2 cup vegetable shortening

3. Bake the cookies for 14 minutes in a preheated 325°F oven.

Cookie chemistry: We're taking a 180° turn from our crunchy cookies, substituting higher-moisture brown sugar and butter for their lower-moisture counterparts: granulated sugar and vegetable shortening. That, plus a shortened baking time, yields a cookie that's soft and chewy all the way through.

You'll notice these cookies use less sugar than the original recipe, too. Why is that?

Cookie chemistry (9)

Because the less sugar you use, the less cookies will spread. Above is a mistake I made along the way: one batch of cookies I made had 50% less sugar than it should have. See the difference in spread? (Actually, I liked this 50% less sugar cookie; it tasted plenty sweet, and its butter flavor was more apparent).

Considering I was using all butter (for its extra moistness) in my soft/chewy cookies, I didn't want to use the full ration of sugar as well, fearing the cookies would spread too much.

Cookie chemistry (10)

Some sources call for using bread flour to yield a chewier cookie. I wanted to believe in this, I really did, but the three tests I did showed no difference in chewiness between cookies made with King Arthur Unbleached Bread Flour, and those made with King Arthur Unbleached All-Purpose Flour.

Cookie chemistry (11)

Corn syrup is also recommended by some for extra-chewy cookies. And while I tried adding 2 tablespoons corn syrup to the dough along with the substitutions listed above, I didn't like the result: somewhat glossy, unattractive cookies that had no more chew than their non-corn syrup brethren.

My co-blogger, Susan Reid, says corn syrup is the only way to make "bendy" cookies – but I'll leave that for a future post.

Cookie chemistry (12)

I baked a LOT of chocolate chip cookies over the course of several days in putting together this post. Let me share some additional takeaways with you:

• The chips ratio: My favorite ratio of chocolate chips to cookie is 1 cup chips for every cup of flour in the recipe. This yields a cookie with a generous amount of chips, but not one that seems more gooey chocolate than crunchy cookie.

• Chill out: I discovered awhile ago that letting cookie dough chill for 30 minutes before baking improves cookies' flavor and helps control their spread. I also know that a fully heated oven is critical to cookie success. So make your cookie dough; put it into the fridge; then turn on the oven. Thirty minutes later, your dough will be chilled and your oven fully preheated.

And while we're on the subject – use an in-oven thermometer. The preheating times on ovens are notoriously inaccurate. Only an in-oven thermometer will tell you, for sure, whether your oven's up to temperature and ready to bake.

• Bake a test batch: The perception of crunchy vs. crisp vs. chewy is due somewhat to each person's own personal perception. In addition, all ovens bake slightly differently.

The baking times I give here work for my oven, and yield cookies that I taste as crunchy, crisp, or chewy. To nail down your own baking times, bake just 3 or 4 cookies to start. Let them cool sufficiently for you to see if they're the texture you're after.

Yes, this seems wasteful, letting your hot oven sit empty while cookies are cooling enough to assess their texture. But how much more wasteful is it to make an entire batch of cookies and then, 20 minutes after they're out of the oven, you decide they're not the texture you were looking for?

Cookie chemistry (13)

• Parchment makes a difference: All of my tests were done using parchment-lined, light-colored aluminum baking sheets (including the disastrous first take on chewy cookies pictured above).

Cookies baked on parchment won't spread as much; and their bottoms won't brown (or potentially burn) as quickly. For the complete results of our parchment/no parchment cookie baking tests, see our post, the secret to perfectly browned cookies.

We've arrived at the end of our chocolate chip cookie journey. And I can hear many of you saying, "Yes, but my chocolate chip cookie recipe uses butter and brown sugar and makes the perfect crunchy chocolate chip cookie!"

I have no doubt you can make crisp cookies with butter and brown sugar, and soft cookies with vegetable shortening and white sugar. If you already have your own "perfect" chocolate chip cookie recipe – stick with it! Like so many good things in life, there's more than one way to skin a cat – or bake a chocolate chip cookie.

Cookie chemistry (2024)

FAQs

What is the cookie model in chemistry? ›

According to the Thomson's Plum Pudding Model of an atom, the structure of an atom is similar to a chocolate chip cookie where the electrons can be represented as the chocolate chips and the positive charge as dispersed in the rest of the cookie.

What is the chemical equation for baking a cookie? ›

While baking, the heat allows for the sucrose (sugar) to break down into glucose and fructose. This causes a polymer chain which allows for the cookie to have a light brown, shiny crust. When the sodium bicarbonate (baking soda) absorbs heat, a chemical reaction occurs – 2NaHCO3 –> Na2CO3 + H2O + CO2.

What is the chemistry behind baking? ›

One of the most important reactions in baking is the Maillard reaction, which occurs when heat causes amino acids and reducing sugars to combine and form the delicious brown crust that we all love.

What happens chemically when you bake cookies? ›

The Maillard reaction takes place.

The Maillard reaction is a chemical reaction between amino acids and reducing sugars, so along with the caramelizing sugar, proteins in the cookie begin to brown, producing a rich, nutty, toasted flavour. This is the same reaction that occurs in bread and seared steak.

What makes cookies cakey vs chewy? ›

Sugar dissolved in baking forms a syrup as the dough heats up. Different types of sugars affect the texture because they absorb different amounts of water. Remember moisture is the key! White sugar creates crispier cookies and brown sugar creates chewier cookies.

What ingredient holds cookies together? ›

Flour is the main ingredient that provides structure in a cookie – without it, there would be no cookie! The gluten in flour forms a web of sorts – the framework that catches the air bubbles/gasses given off during rising. This helps provide the structure.

What is cookie theory? ›

While the Cookie Theory is simply a nice thing for someone you work with, it's also helping you start a conversation and therefore a connection with a co-worker. You give them the cookie, stop to chat, and make a meaningful conversation. Make sure you do more than small talk.

What elements make up cookies? ›

The foundation of any cookie recipe consists of five types of ingredients: fat, sugar, flour, a rising agent, and a binding agent. Fat is added for flavor and controls how chewy or crunchy the cookie is. More fat = a chewier cookie, less fat = a crunchier cookie.

What is the chemistry of baking sugar cookies? ›

As the sugars break down, they caramelize and create that signature fresh-baked cookie odor. Then the proteins in the egg and flour succumb to the Maillard reaction. This reaction occurs when sugars and proteins are heated together, for delicious results. The Maillard reaction is responsible for cookies' toasty flavor.

What makes a cookie fluffy? ›

Butter keeps cookies fluffy in two ways. First, creaming cold butter with sugar creates tiny, uniform air pockets that will remain in the dough it bakes up. Second, cold butter naturally takes a longer time to melt in the oven.

What makes cookies flat? ›

Oven temperatures are a crucial factor in baking. If your cookies consistently come out flat, you may have selected the wrong baking temperature. If you bake cookies using too much heat, the fats in the dough begin to melt before the other ingredients can cook together and form your cookie's rise.

Is baking a cookie a physical or chemical change? ›

Baking cookies is a chemical change. This is because new substances are formed during the process, such as carbon dioxide gas from the reaction of baking soda or powder with other ingredients. The process is irreversible under normal conditions, which is a key characteristic of chemical changes.

Do you need chemistry for baking? ›

Baking is an excellent example of how chemistry and cooking are interrelated. For example, sugars brown in heat, creating that delicious pastry or cake, cookie dough caramelizes, and leavening agents, such as yeast and baking powder, give dough that light and fluffy appearance.

What is the physics behind baking? ›

Chemistry, as you mix different edible chemicals to create dough or batter, with tiny air bubbles trapped inside. Biology, as the culture of yeast provides carbon dioxide to make your bread rise. And physics, as those trapped gases expand and give the rise to the bakes.

Is cookie a element compound or mixture? ›

Answer and Explanation:

A chocolate chip cookie is an example of a heterogeneous mixture because it is made up of different materials that can be easily distinguished.

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