The chemical reaction that makes century eggs black (2024)

The dish arose in China as a novel way to preserve fresh eggs.

Century eggs, sometimes also called thousand-year-old eggs, are one of the most misunderstood dishes in Chinese cuisine.

With their black-brown exterior, gelatin-like texture, and runny greenish-black yolk, the preserved eggs are often a sight gag on late-night comedy shows. James Corden, host of The Late Late Show, frequently uses them in his truth-or-dare segment with celebrities.

Common misconceptions about century eggs revolve around why they’re black, including speculation of unsavory ingredients like horse urine, toxic lead, and artificial food coloring.

(Read more: Century egg myths: No, they’re not made of horse urine or a hundred years old)

But the real reason for the eggs’ unique color is a simple chemical reaction, the same one that gives cooked bacon and fresh toast their brown color.

The science behind century eggs

Century eggs are essentially preserved eggs. Their production in China likely arose to preserve excess supplies of fresh eggs. Nowadays, duck eggs are often used to make them.

The eggs are covered in mud mixed with salt, soda ash, and quicklime. The soda ash and quicklime react with water to form sodium hydroxide.

The chemical reaction that makes century eggs black (1)

Through osmosis, the sodium hydroxide breaks down protein in the egg and hardens the albumen. That’s why when you open a century egg, the inside is gelatin.

(Read more: ‘We took it off the menu because it was a little weird’: Junzi Kitchen head chef on the challenges of selling Chinese food in New York)

The eggs are left to sit for up to three months. The mud creates a vacuum seal that keeps out bacteria and other microorganisms, which means century eggs areready to eat and don’t need to be cooked.

But why are they black?

The century egg’s distinct hue comes from the Maillard reaction, a natural browning effect that’s accelerated in a highly alkaline environment.

The chemical reaction that makes century eggs black (2)

Sodium hydroxide is alkaline. As it breaks down the egg’s protein into glucose and amino acids, the two chemicals react. This reaction, called the Maillard reaction, produces the distinct color of century eggs.

It’s also what causes browning when you fry bacon on a pan or roast meat in an oven.

Clarissa Wei

Clarissa Wei is a senior reporter at Goldthread. She spent the bulk of her career as a freelance journalist and has written for outlets like VICE, CNN, Eater, among others. Clarissa has backpacked to over a dozen provinces in China and was once a volcano hiking guide in Nicaragua.

ExplainerCentury egg
The chemical reaction that makes century eggs black (2024)

FAQs

The chemical reaction that makes century eggs black? ›

Sodium hydroxide is alkaline. As it breaks down the egg's protein into glucose and amino acids, the two chemicals react. This reaction, called the Maillard reaction, produces the distinct color of century eggs. It's also what causes browning when you fry bacon on a pan or roast meat in an oven.

What is the chemical reaction in the century egg? ›

Sodium hydroxide, produced by the reaction of sodium carbonate, water, and calcium oxide in the brine or coating paste, penetrates the eggshell, turning the egg white into a brown, semi-translucent gelatinous texture and the egg yolk into a dark green semi-solid or solid in 20–50 days depending on the method used (Wang ...

What is the Maillard reaction in the century egg? ›

The egg white or albumen changes colour to a brown or greenish brown, with a gel-like texture; the egg yolk changes colour to blackish green, grass green or dark brown. The colour change has been partly contributed to the Maillard reaction between the glucose of the albumen and amino acids.

What is the science behind century eggs? ›

Chemical Fermentation

water (H2O) react to produce sodium hydroxide (NaOH). The NaOH diffuses through the eggshell and disassembles the 3-dimensional protein structure of the egg white. The protein fragments interact with one another, and with water, and the runny egg white gets converted to a gel.

What makes black eggs black? ›

The water that they are boiled in contains sulfur and iron, thus giving the shells their unique color. The black eggs, commonly called Kuro-Tamago by the locals, are perfectly safe, although they may smell like sulfur.

Why do century eggs turn black? ›

Sodium hydroxide is alkaline. As it breaks down the egg's protein into glucose and amino acids, the two chemicals react. This reaction, called the Maillard reaction, produces the distinct color of century eggs. It's also what causes browning when you fry bacon on a pan or roast meat in an oven.

What is the chemical reaction in eggs? ›

To begin with, in a raw egg the long protein molecules are individually coiled up. However, as we heat them, these chains begin to unfold, a process known as 'denaturing'. Once unravelled, the proteins form a three-dimensional network, trapping water into tiny pockets in the network, and causing solidification.

What are 3 results caused by the Maillard reaction? ›

While they still don't entirely understand it, they do know the basics: The Maillard reaction is many small, simultaneous chemical reactions that occur when proteins and sugars in and on your food are transformed by heat, producing new flavors, aromas, and colors.

How is it safe to eat a century egg? ›

If made properly, century eggs are completely safe. There was once a rumour that century eggs were made by soaking them in horse urine, but that's not true. If you buy your century eggs from a shop, check the label to make sure they weren't made with lead oxide – eating foods with lead oxide can be harmful.

How long does a century egg ferment? ›

Century eggs take about 4-5 weeks to make, a few minutes to work up the courage to open, and a few seconds to eat. Traditionally century eggs were made by preserving chicken or duck eggs in a mixture of salt, lime and ash, then wrapping in rice husks for several weeks.

Can Muslims eat century eggs? ›

Brief Answer: The ruling of eating the century egg is halal based on the Islamic legal maxim which states “The original rule for food is halal unless there is a dalil which states on its prohibition”.

How do century eggs not rot? ›

Century eggs are a type of egg traditionally made in China and other Asian countries, like Hong Kong and Taiwan, by preserving the egg for many weeks or months in a mixture of clay, salt, wood ash, and quicklime.

How many century eggs can you eat in a day? ›

The eggs are high in calories. So it's essential to consume them in moderation. Limiting your intake of century eggs to 1 or 2 eggs per day is recommended as a general guideline. It allows you to enjoy their unique flavor and nutritional benefits without over consuming them.

Why did my eggs turn black? ›

Black or green spots inside the egg may be the result of bacterial or fungal contamination of the egg. If you come across an egg with black or green spots discard the egg. Off color egg whites, such as green or iridescent colors may be from spoilage due to bacteria.

How to make century eggs at home? ›

Ways to make century eggs

Using option one, mix rice hulls, clay ash, lime powder, and salt in an earthen pot. Place the duck eggs in the pot and cover them completely with the mixture. Cover the pot and place it in a dry, dark area for six to eight weeks. If you do not have clay ash, use a mix of clay or wood ash.

What is the chemical reaction in the rubber egg experiment? ›

A chemical reaction occurs with between the vinegar and calcium carbonate. This reaction will create carbon dioxide. If you look closely, you may see tiny bubbles forming on the side of the eggshell and float to the surface. The reaction will eventually dissolve the eggshell.

What is the chemical reaction in a hard boiled egg? ›

“When an egg is cooked for too long and/or at too high a temperature, the sulfur in the egg white combines with the iron in the yolk and creates ferrous sulfide, which has a green tint,” she explains. Unfortunately, this chemical reaction—which scientists call denaturation—isn't limited to hard-boiled eggs.

Why does century egg taste like ammonia? ›

Through the process, the yolk becomes dark greenish grey in color, with a creamy consistency and strong flavor due to the hydrogen sulfide and ammonia present, while the white becomes dark brown in color, with a translucent jelly-like appearance and salty flavor.

What is the chemical reaction that took place in the rubber egg experiment clue the primary component of the egg shells is calcium carbonate? ›

Acetic acid CH3COOH reacts with calcium carbonate CaCO3 contained in an egg shell, thus dissolving the latter. This reaction yields calcium acetate. The egg itself becomes soft and rubbery to touch.

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