The Science of Thickening Agents — The Culinary Pro (2024)

Thickening Agents

The goal of thickening a sauce is to add viscosity, texture, and mouthfeel while helping the food to linger on the taste buds. Un-thickened sauces may have a more immediate flavor punch but don’t cling to the tongue unless they are high in gelatin (and glutamates), which is found in meats, poultry, and fish. Thickeners in the form of starches, like flour or cornstarch, add body to a sauce. However, they can mask flavors and require more seasoning to compensate for this difference.

REDUCTIONS, EMULSIONS, AND SUSPENSIONS

Methods for thickening sauces, soups, and stews include reductions, emulsions, and suspensions.

  • Reduction concentrates liquids and flavors by simmering and reducing the volume through evaporation. In meat-based sauces, naturally occurring gelatins help to add body.

  • Emulsions, or colloids, occur when wheat or refined starches swell and gelatinize in hot liquids. They are also created when liquids and fats combine and are agitated to make mayonnaise or hollandaise sauce.

  • Suspensions are created by blending various ingredients into fine particles to create a hom*ogenous mixture, such as in a tomato sauce or bean soup.

REDUCTION SAUCES

Sauces prepared using the reduction method have an intense flavor unobstructed by thickening agents. The simplest sauces are made from rendered pan juices, known as a jus, from roasted or sautéed proteins (meat, poultry, or fish) and enhanced with a prepared stock, wine, or other suitable liquid. These sauces are simmered to reduce the liquid and concentrate the flavors. A glace, or glaze, is a reduced stock cooked to a syrup-like consistency, resulting in a viscous, intensely flavored sauce.

EMULSIONS

Wheat flour is used extensively in professional kitchens as a thickening agent. Although it can be combined with water to create a whitewash, it is more commonly mixed with fat, which surrounds the starch granules and prevents clumping when added to hot liquids. Roux is a combination of equal parts by weight of flour and fat cooked to gelatinize the flour before use. A beurre manie is an uncooked roux consisting of equal parts by volume of softened butter and blended flour.

WHEAT FLOUR: THICKENING WITH ROUX

Four types of roux are classified by color and length of cooking time, from white to blonde and brown to black. Although a basic ratio for roux is equal parts fat and flour by weight, the extended cooking time for a dark roux reduces the flour’s thickening power, so the ratio is adjusted up to three parts flour to two parts fat. Clarified butter is often used because of its preferred flavor, but vegetable oils or other rendered animal fats (chicken, pork, or duck) can also be used. A roux should be stiff and not runny. In a professional kitchen, a roux is often prepared in batches and held ready to use when needed.

Uses: Gumbo, Cajun Cuisine

  1. Cook while stirring to give it a dark brown-to-black color.

  2. Cook for about 60 minutes to give it a rich color.

  3. Alternately cover with a tight lid and cook in a 350˚F (177˚C) oven.

OTHER WHEAT-BASED OPTIONS

Brown flour, also called a dry roux, is used in Cajun and Caribbean cooking as a thickening agent. It is prepared in a cast iron skillet on the stove with continuous stirring or placed on a sheet pan in a 350°F (175˚C) oven for 1 hour and stirred about every 15 minutes. The flour is added directly to the liquid or combined with fat to create a roux. It is shelf-stable and can be combined with fats to develop an instant brown roux.

Beurre manié —Also called kneaded butter, beurre manié is equal parts of softened butter and flour that are worked together into a smooth paste. It is used at the last minute to adjust the consistency of sauces, soups, and stews. Add a little at a time and allow to cook so the flour can swell and absorb liquid. Since the flour is raw, simmering it for a few minutes is a good idea to cook out the taste.

Bread Crumbs—Cooked wheat products, including bread, crackers, and cookies, crumbled or pulverized, are economical ways to thicken soups, sauces, and stews. This practice has been documented since ancient Roman times and is useful for leftover stale bread.

ROUX TO LIQUID RATIOS

For medium-thickness sauces, use a ratio of 8 parts liquid to one part roux, equal to 16 oz. (450 g) of roux for each gallon (4 liters) of liquid. The amount of roux will vary depending on the desired thickness (see chart). It also depends on how long the roux is cooked. That’s because during the cooking process, the grains of the flour swell, and the cell structure weakens under prolonged heat, causing the grains to collapse. A brown roux loses up to 50% of its thickening power, requiring more roux. That’s why the flour ratio is increased when preparing a darker roux.

When thickening a soup or sauce, the liquid may be added to the roux, or the roux may be added to the liquid. Although the roux can be used cold or warm, it’s best not to have both the liquid and the roux hot because the roux can become lumpy in the liquid. Wheat flour needs about 20 minutes to swell and achieve its full thickening potential, so be patient and allow it to cook sufficiently.

Refined Vegetable Starches

Refined starches are popular as thickening agents because they are lighter than a roux, neutral-flavored, and swell quickly when added to hot liquids. Refined starches, including arrowroot, cornstarch, potato starch, and rice flour, are also preferred alternatives for gluten-intolerant diets. These starches are mixed with water to create a slurry that is added at the end of the cooking process because prolonged heat weakens their power.

Warm emulsions mix fats and liquids that generally do not easily combine. Rapidly whisking a liquid while slowly adding fat causes the fat molecules to split into tiny droplets that adhere to the liquid, creating a thick viscosity. Liquids and fats, when combined, create temporary emulsions, but adding ingredients like egg yolks, reduced cream, or spices will stabilize these mixtures. Sauces like Hollandaise and Béarnaise are two examples of egg yolk and butter emulsions, and a beurre blanc sauce is an example of a liquid and butter emulsion stabilized with cream. Mayonnaise is an uncooked version. These sauces are time and temperature-sensitive and are usually prepared as needed just before the start of service.

Warm emulsion sauces can’t be held in a hot box or steam table because the temperatures are usually too high, causing them to separate. Instead, keep in a warm bath or insulated at 120°F/49˚C in an insulated food container and discard after a maximum of 4 hours.

LIAISON OF EGG YOLKS AND CREAM

A liaison is composed of egg yolks and cream and is used to enrich and thicken soups, sauces, and stews at the end of the cooking process. Once a liaison is added, never allow it to boil because the egg yolks will curdle and have a grainy appearance. Use a ratio of 4 parts cream to 1 part egg yolks.

Dairy Products

Butter is an emulsion in itself, swirled into sauces at the end of the cooking process, known as Monter au Beurre. Butter will thicken slightly, but it also adds richness.

Cream – Added to enrich a sauce, cream as a thickener must be reduced to provide viscosity to liquids. It works best when reduced by about one-third of its volume to concentrate fat globules to about 55% of the total volume.

THICKENING WITH SUSPENSIONS

Grains, legumes, root vegetables, nuts, and seeds are gluten-free thickening agents used in various ethnic and vegetarian preparations. Raw rice is a traditional thickener in bisque soup, while raw diced potatoes are a natural thickener in cream soups. For kitchen efficiency, leftover rice and potato purees can be repurposed into soups rather than thrown out. Pureed fruits and vegetables are the basis for classic Italian tomato sauces and French coulis, while nuts and seeds are used in African and vegetarian cooking.

The Science of Thickening Agents — The Culinary Pro (2024)

FAQs

What are the science of thickening agents? ›

Polysaccharide thickeners include starches (e.g., flour, cornstarch, arrowroot, and tapioca) and fiber-based thickeners (e.g., guar gum, xanthan gum, pectin, and cellu- lose). All work to thicken food products because their long strands of fiber or starch easily absorb liquid and “thicken” liquid mass.

What is a thickening agent in cooking? ›

A food thickener is a thickening agent that increases the viscosity of a liquid mix without interfering with its other properties. Knowing how to thicken food is essential for preparing many recipes; most sauces, gravies, soups, and even desserts are thickened with some kind of starch.

What is a thickening agent that can be cooked for different amount of time to produces a lighter or darker color? ›

Each of the five mother sauces is made with a different liquid, and a different thickening agent—although three of the mother sauces are thickened with ​a roux, in each case the roux is cooked for a different amount of time to produce a lighter or darker color.

What is the scientific name for thickening? ›

In the process of thickening (also called sedimentation), the solids in a suspension settle under the influence of gravity in a tank and form a thick pulp.

What can thickening agents prevent? ›

People who have difficulty swallowing thin liquids usually must drink thickened liquids. Drinking thickened liquids can help prevent choking and stop fluid from entering the lungs. Thickened liquids move slower than thin liquids giving your body more time to protect the airway. Some liquids are naturally thick.

What is the best thickening agent? ›

Potato starch is the most potent of the bunch, with long starch molecules that quickly tangle with each other and thicken a liquid.

What is the most common form of thickening agent? ›

Cornstarch. Cornstarch is the most common thickening agent used in the industry. It is mixed with water or juice and boiled to make fillings and to give a glossy semi-clear finish to products. Commercial cornstarch is made by soaking maize in water containing sulphur dioxide.

What is a natural thickener? ›

Natural food thickeners are substances derived from plants or other natural sources. Examples include agar agar, arrowroot, and chia seeds. They offer a range of unique properties and health benefits.

Can I just add flour to thicken sauce? ›

To use flour as a thickening agent: Use two tablespoons flour mixed with ¼ cup cold water for each cup of medium-thick sauce. Thoroughly mix in the water to prevent lumps. After stirring the combined flour and water into the sauce, cook and stir over medium heat until thickened and bubbly.

What thickener can be frozen? ›

Although not modified food starches, arrowroot, and tapioca can be used to thicken products for freezing and yield satisfactory freeze-thaw results.

Does roux color matter? ›

What color roux should you use for your dish? Use a light roux when you want to thicken sauces (like béchamel) without adding much flavor; opt for a dark roux when you want the finished dish to have nutty, caramelized undertones.

What is the mechanism of thickening agent? ›

Formulations can be thickened with soluble swellable polymers or colloidal structures. Gelling agents may be used to form a gel by dissolving in the liquid phase as a colloid mixture with a weakly cohesive internal structure. Other thickeners may act through discrete particles adhering or interlocking.

What is the principle of thickener? ›

Solids settling out of or through the feed layer pass into a critical zone. The solids then pass into the compression zone, where they are subjected to an increasing solids stress (arising from the weight of solids above) as they move deeper into the compressing layer. They are thus compacted or thickened.

How do thickeners work in chemistry? ›

Some thickening agents are gelling agents (gellants), forming a gel, dissolving in the liquid phase as a colloid mixture that forms a weakly cohesive internal structure. Others act as mechanical thixotropic additives with discrete particles adhering or interlocking to resist strain.

What is the science behind a roux? ›

A roux works thanks to the thickening power of starch. Starch is made up of minuscule granules, each of which contains two different forms of starch molecules. First are the long, thin chains of glucose known as amylose; the second are branched clusters of glucose known as amylopectin.

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